Reversible Addition-Fragmentation Chain Transfer Polymerization of Acrylamide Derivatives
| dc.contributor.advisor | Nagy, Tibor | |
| dc.contributor.author | Alakbarov, Mahammad | |
| dc.contributor.department | DE--Természettudományi és Technológiai Kar--Kémiai Intézet | |
| dc.date.accessioned | 2023-04-26T07:55:44Z | |
| dc.date.available | 2023-04-26T07:55:44Z | |
| dc.date.created | 2023-04-20 | |
| dc.description.abstract | In my diploma work, I synthesized poly(N-acryloylmorpholine), poly(diacetoneacrylamide) homopolymers and NAM/DAAM random copolymers applying RAFT, in other words, polymerization of reversible addition-fragmentation chain transfer technique. Methods were adopted and modified to synthesize well defined polymers in a diverse array of chemical composition and molecular mass. The structure of produced polymers was determined by MALDI-TOF MS. Distinct factors like concentration of monomers, chain transfer agent, initiator for polymerization were investigated to optimize a synthetic method. Using the collecting data of PNAM, PDAAM homopolymers and NAM/DAAM random copolymer sample peaks, I calculated Mw(weight average molecular weight), Mn(number average molecular weight) as well as PDI(polydispersity index) of them. I calculated the homopolymers' polymerization degree for exact peaks from PNAM and PDAAM samples. MR1 and m/z ratio data confirmed the chemical composition of NAM/DAAM random copolymers using IsotopePattern. | |
| dc.description.corrector | LB | |
| dc.description.course | Chemical Engineering | |
| dc.description.degree | MSc/MA | |
| dc.format.extent | 49 | |
| dc.identifier.uri | https://hdl.handle.net/2437/350862 | |
| dc.language.iso | en | |
| dc.rights.access | Hozzáférhető a 2022 decemberi felsőoktatási törvénymódosítás értelmében. | |
| dc.subject | Homopolymers | |
| dc.subject | Copolymers | |
| dc.subject | Kinetics | |
| dc.subject | Mass spectrometry | |
| dc.subject.dspace | DEENK Témalista::Kémia | |
| dc.title | Reversible Addition-Fragmentation Chain Transfer Polymerization of Acrylamide Derivatives |